An Introduction to Macromolecules by Leo Mandelkern (auth.)

By Leo Mandelkern (auth.)

The reception of the unique quantity by means of scholars, pedagogues, and reviewers has been such a lot pleasant. it sounds as if to have either chuffed a necessity and served an invaluable academic objective. as a result, a few ten years later it's been deemed a good suggestion to carry it modern, if basically in a touch multiplied shape. the aim for penning this booklet and its point stay an analogous. Many new polymers were synthesized within the final decade that experience stumbled on significant and novel makes use of. Examples of those purposes are incorporated during this re-creation. significant advances have additionally been made in biophysics and in molecular biology, in addition to in our knowing of ordinary strategies on a molecular point. superior between those has been the improvement of recombinant DNA know-how. With it has come the opportunity of huge scale synthesis of hormones and proteins. those new advancements have additionally been included into the current quantity. it's my desire that this re-creation will nonetheless have a common entice scholars in all the traditional sciences no matter what their significant curiosity. it's going to even be of use and inter­ est to these beginning business or educational careers who've no longer had an intensive historical past in macromolecular science.

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Extra resources for An Introduction to Macromolecules

Sample text

The highly extended character of these chains endow them with unique molecular properties that lead to substances possessing unusual physical and mechanical properties (see Chapter 5). These type chains do not display random coil behavior except in the limit of exceptionally high molecular weights. On the other hand, chains characterized by smaller values of the constant C achieve random, or statistical, conformation at degrees by polymerization that are the order of 20-50. The degree of polymerization is defined as the number of repeating units in a molecule.

This capability for internal rotation allows a chain molecule to generate a large number of different conformations. 1. Polyethylene chain. one or more single bonds. 1 is thus one that has conveniently, but arbitrarily, been selected from among many. We must now ask what we mean by internal rotation and how this operation can lead to many different structures. The fundamental principle involved here can be easily understood by studying a simple molecule such as ethane C2 H6 • This molecule contains but one rotatable bond, the carbon-carbon single bond.

This model represents a polyethylene conformation for a chain consisting of 150 carbon atoms. In both these models, the tortuous, random-like structure and highly irregular shape of the molecule becomes readily apparent. The molecule is highly coiled and very compact, since the end-to-end distance -; is very much less than the extended, or contour, length of the chain. 1 yields an extended molecule of rod-like form. However, it represents but one of the large number of conformations that can be generated.

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An Introduction to Macromolecules by Leo Mandelkern (auth.)
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